钒掺杂钨青铜内通道氨配位的钌单原子用于高效析氢反应

doi:10.1016/S1872-2067(23)64489-4

催化学报 ›› 2023, Vol. 51: 80-89.DOI: 10.1016/S1872-2067(23)64489-4

钒掺杂钨青铜内通道氨配位的钌单原子用于高效析氢反应

韩策^a, 梅丙宝^c, 张庆华^d, 张慧敏^a^,^b, 姚鹏飞^a^,^b, 宋平^a, 宫雪^a, 崔培昕^e, 姜政^c^,^*(), 谷林^f^,^*(), 徐维林^a^,^b^,^*()

^a中国科学院长春应用化学研究所, 吉林省低碳化工动力重点实验室, 电分析化学国家重点实验室, 吉林长春130022
^b中国科学技术大学, 安徽合肥230026
^c中国科学院上海应用物理研究所, 上海201204
^d中国科学院物理研究所, 北京凝聚态物理国家实验室, 北京100190
^e中国科学院土壤研究所, 土壤环境与污染修复重点实验室, 江苏南京210008
^f清华大学材料科学与工程系, 北京国家电子显微镜中心和先进材料实验室, 北京100084

收稿日期:2023-04-28 接受日期:2023-07-10 出版日期:2023-08-18 发布日期:2023-09-11
通讯作者: *电子信箱: jiangzheng@sinap.ac.cn (姜政), l.gu@iphy.ac.cn (谷林), weilinxu@ciac.ac.cn (徐维林).
基金资助:
国家自然科学基金(22102172);国家自然科学基金(22072145);国家自然科学基金(22005294);国家自然科学基金(21925205);国家自然科学基金(21721003);国家重点研发计划(2022YFA1203400)

Atomic Ru coordinated by channel ammonia in V-doped tungsten bronze for highly efficient hydrogen-evolution reaction

Ce Han^a, Bingbao Mei^c, Qinghua Zhang^d, Huimin Zhang^a^,^b, Pengfei Yao^a^,^b, Ping Song^a, Xue Gong^a, Peixin Cui^e, Zheng Jiang^c^,^*(), Lin Gu^f^,^*(), Weilin Xu^a^,^b^,^*()

^aState Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Jilin, China
^bUniversity of Science and Technology of China, Hefei 230026, Anhui, China
^cShanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201204, China
^dBeijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
^eKey Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, Jiangsu, China
^fBeijing National Center for Electron Microscopy and Laboratory of Advanced Materials, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, China

Received:2023-04-28 Accepted:2023-07-10 Online:2023-08-18 Published:2023-09-11
Contact: *E-mail: jiangzheng@sinap.ac.cn (Z. Jiang), l.gu@iphy.ac.cn (L. Gu), weilinxu@ciac.ac.cn (W. Xu).
Supported by:
National Natural Science Foundation of China(22102172);National Natural Science Foundation of China(22072145);National Natural Science Foundation of China(22005294);National Natural Science Foundation of China(21925205);National Natural Science Foundation of China(21721003);National Key Research and Development Program of China(2022YFA1203400)

摘要/Abstract

摘要：

通过电解水制备氢气是实现“碳中和”目标的理想途径之一.因此,可在全pH条件下使用的氢析出(HER)催化剂的研发是近年来电催化领域的研究热点.原子级分散的催化剂,能够在保留铂族金属(PGM)固有活性的同时,降低催化剂中PGM的用量.虽然可以通过X射线吸收光谱(XAS)来表征原子分散的PGM电催化剂的配位环境，但目前对原子空间分布的控制仍然具有挑战.
本文制备了钒掺杂钨青铜内通道氨配位的钌单原子催化剂(Ru/V-NHWO),用于全pH范围内的HER反应.采用X射线衍射(XRD)、高角环形暗场扫描透射电镜(HAADF-STEM)、X射线光电子能谱(XPS)和原位X射线吸收光谱(XAS)等进行表征,研究了钌单原子与V-NHWO载体的结合方式以及构效关系,并采用密度泛函理论(DFT)计算探索了催化剂中诸多位点的活性贡献.在1mol/L KOH,0.5mol/L H₂SO₄和1mol/L磷酸盐缓冲溶液中,其在10mA cm^‒2下的过电位分别为28.0,29.6和40.6mV.同时,在过电位100mV时,质量活性分别达到3930,1941和602.8mA mg^‒1_Ru,数倍于同等条件下的商业铂碳.XRD结果表明,钌的引入可以确保催化剂在氩气条件下热解后仍保持六方钨铵青铜晶相,证明钌与钨铵青铜六方晶体通道内氨物种,即“通道氨”的结合.HAADF-STEM结果表明,钌原子与NHWO间存在强烈相互作用,有助于提升HER性能.XPS和XAS结果表明,W⁵⁺信号出现在引入钌后,峰位置的结合能增加且峰面积降低,说明钌与通道氨之间存在相互作用.N的XPS结果表明,钌的引入导致了金属氨键的形成.XAS结果表明,Ru/V-NHWO/CC中钌单原子和钌团簇共存,钌单原子与通道氨配位,并且钒的引入会诱发V-NHWO中金属键长缩短,这表明催化剂的金属性得到了提升,有利于改善其导电性.
采用DFT计算进一步研究了HER活性的来源.相比于V-NHWO载体和钌团簇修饰的V-NHWO,以单原子形式结合的钌具有更低的水解离能垒,该能垒在氨桥接的钌双原子垂直插入、钒掺杂和多通道插入等多种因素作用下进一步降低.同时,氢中间体结合能得到了相应的优化而趋近于0eV.此外,差分电荷密度模拟结果表明,氢中间体结合后,V-NHWO对于钌单原子存在明显的供电子行为,有利于HER动力学过程.综上,本工作报道了金属载体对于高分散金属原子空间分布调控的重要作用,可为设计和构筑可应用于诸多能源转换过程的新型原子级分散催化剂提供参考.

关键词: 单原子钌, 通道氨, 六方晶通道, 钨青铜, 析氢反应

Abstract:

Regulation of the atomic distribution is crucial for the development of atomically dispersed electrocatalysts. In this study, atomic Ru coordinated by channel ammonia in V-doped tungsten bronze (Ru/V-NHWO, Ru 0.44 wt%, V 0.45 wt%) was used as a high-performance catalyst for the hydrogen evolution reaction (HER), demonstrating remarkable mass activity in a wide pH range. Atomic Ru with a regulated spatial distribution and electronic structure was achieved owing to its unique coordination with the ammonia species in the hexagonal channels of V-NHWO. V doping in NHWO led to enhanced intrinsic activity and conductivity. Theoretical calculations revealed that the multichannel, vertically integrated Ru sites in the V-doped channels, as well as the coexisting Ru sites without multichannels or V-doping, improved the free energy of water dissociation and hydrogen sorption, which boosted the HER activity. Our study paves a new way for constructing atomically dispersed materials with a regulated spatial distribution for diverse applications.

Key words: Atomic Ru, Channel ammonia, Hexagonal crystal channel, Tungsten bronze, Hydrogen evolution reaction

韩策, 梅丙宝, 张庆华, 张慧敏, 姚鹏飞, 宋平, 宫雪, 崔培昕, 姜政, 谷林, 徐维林. 钒掺杂钨青铜内通道氨配位的钌单原子用于高效析氢反应[J]. 催化学报, 2023, 51: 80-89.

Ce Han, Bingbao Mei, Qinghua Zhang, Huimin Zhang, Pengfei Yao, Ping Song, Xue Gong, Peixin Cui, Zheng Jiang, Lin Gu, Weilin Xu. Atomic Ru coordinated by channel ammonia in V-doped tungsten bronze for highly efficient hydrogen-evolution reaction[J]. Chinese Journal of Catalysis, 2023, 51: 80-89.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(23)64489-4

https://www.cjcatal.com/CN/Y2023/V51/I8/80

图/表 4

Fig. 1. (a) Schematic illustration for the fabrication of Ru/V-NHWO nanorod arrays supported by CC substrate. (b-e) SEM, TEM, atomic HAADF-STEM, and elemental mapping images of Ru/V-NHWO/CC.

Fig. 2. (a) XPS results of W 4f for V-NHWO/CC, Ru/NHWO/CC, and Ru/V-NHWO/CC. (b) XPS results of Ru 3d for Ru/NHWO/CC and Ru/V-NHWO/CC. (c) XPS results of N 1s for V-NHWO/CC, Ru/NHWO/CC, and Ru/V-NHWO/CC. Normalized Ru K-edge XANES curves (d), and FT (e) and WT (f) of k3-weighted EXAFS signals for Ru foil, RuO2, Ru/NHWO/CC, and Ru/V-NHWO/CC. Normalized W L3-edge XANES curves (g), and FT (h) and WT (i) of k3-weighted EXAFS signals for W foil, WO3, Ru/NHWO/CC, and Ru/V-NHWO/CC.

Fig. 3. iR-corrected LSV curves (a), Tafel plots (b), Nyquist plots (c), and electrochemical double-layer capacitances (d) of bare CC, V-NHWO/CC, Ru/NHWO/CC, and Ru/V-NHWO/CC in 1 mol L?1 KOH electrolyte. (e-g) iR-corrected LSV curves of Ru/V-NHWO/CC, Pt/C/CC, and Ru/C/CC. (h) Chronopotentiometric tests of Ru/V-NHWO/CC at 10?mA cm?2 for 20?h in 1 mol L?1 KOH, 1 mol L?1 PBS, and 0.5 mol L?1 H2SO4 electrolytes.

Fig. 4. (a) Structural models of SA Ru/V-NHWO, Ver-Ru/V-NHWO, and Ru/V-NHWO. DFT-calculated reaction energy diagrams of water dissociation (b) and H intermediate sorption (c) for V-NHWO, Ru NP/V-NHWO, SA Ru/V-NHWO, Ver-Ru/V-NHWO, Ru2 site, and Ru/V-NHWO. Charge-density difference analysis for Ru/V-NHWO before (d) and after (e) H-intermediate sorption. Yellow represents electron agglomeration, and blue represents electron dissipation.

参考文献

[1]	X. Jiang, H. Jang, S. Liu, Z. Li, M.G. Kim, C. Li, Q. Qin, X. Liu, J. Cho, Angew. Chem. Int. Ed., 2021, 60, 4110-4116.
[2]	Y. Huang, J.-J. Wang, Y. Zou, L.-W. Jiang, X.-L. Liu, W.-J. Jiang, H. Liu, J.-S. Hu, Chin. J. Catal., 2021, 42, 1395-1403.
[3]	Q. Chen, Y. Nie, M. Ming, G. Fan, Y. Zhang, J.-S. Hu, Chin. J. Catal., 2020, 41, 1791-1811.
[4]	B. Zhou, R. Gao, J.-J. Zou, H. Yang, Small, 2022, 18, 2202336.
[5]	S. Xu, Q. Wu, B.-A. Lu, T. Tang, J.-N. Zhang, J.-S. Hu, Acta Phys.-Chim. Sin., 2023, 39, 2209001.
[6]	H. Song, J. Yu, Z. Tang, B. Yang, S. Lu, Adv. Energy Mater. 2022, 12, 2102573.
[7]	Y. Liu, Q. Wang, J. Zhang, J. Ding, Y. Cheng, T. Wang, J. Li, F. Hu, H.B. Yang, B. Liu, Adv. Energy Mater., 2022, 12, 2200928.
[8]	C. Zhang, H. Wang, H. Yu, K. Yi, W. Zhang, X. Yuan, J. Huang, Y. Deng, G. Zeng, Adv. Energy Mater., 2022, 12, 2200875.
[9]	H. Song, M. Wu, Z. Tang, J. S. Tse, B. Yang, S. Lu, Angew. Chem. Int. Ed., 2021, 60, 7234-7244.
[10]	J. Shan, C. Ye, Y. Jiang, M. Jaroniec, Y. Zheng, S.-Z. Qiao, Sci. Adv., 2022, 8, eabo0762.
[11]	Y. Cheng, H. Song, J. Yu, J. Chang, G. I. N. Waterhouse, Z. Tang, B. Yang, S. Lu, Chin. J. Catal., 2022, 43, 2443-2452.
[12]	L. Zou, Y.-S. Wei, C.-C. Hou, C. Li, Q. Xu, Small, 2021, 17, 2004809.
[13]	X. Zheng, P. Li, S. Dou, W. Sun, H. Pan, D. Wang, Y. Li, Energy Environ. Sci., 2021, 14, 2809-2858.
[14]	P. Ou, X. Su, Y. Zeng, F. Zhang, J. Liu, C. Wang, S. Yang, H. Wang, Y. Wen, H. Zhao, CrystEngComm, 2021, 23, 1700-1703.
[15]	W. He, J. Chen, Q. Zhang, H. Cui, C. Wang, Chem. Eng. J., 2022, 436, 135044.
[16]	I. M. Szilagyi, J. Madarasz, G. Pokol, P. Kiraly, G. Tarkanyi, S. Saukko, J. Mizsei, A. L. Toth, A. Szabo, K. Varga-Josepovits, Chem. Mater., 2008, 20, 4116-4125.
[17]	R. Dören, B. Leibauer, M. A. Lange, E. Schechtel, L. Prädel, M. Panthöfer, M. Mondeshki, W. Tremel, Nanoscale, 2021, 13, 8146-8162.
[18]	I. M. Szilagyi, F. Hange, J. Madarasz, G. Pokol, Eur. J. Inorg. Chem., 2006, 3413-3418.
[19]	L. Huo, H. Zhao, F. Mauvy, S. Fourcade, C. Labrugere, M. Pouchard, J.-C. Grenier, Solid State Sci., 2004, 6, 679-688.
[20]	H. Liu, J. Liu, Z. Xu, W. Zhou, C. Han, G. Yang, Y. Shan, Appl. Surf. Sci., 2022, 572, 151482.
[21]	S. Chandrasekaran, P. Zhang, F. Peng, C. Bowen, J. Huo, L. Deng, J. Mater. Chem. A, 2019, 7, 6161-6172.
[22]	C. Cai, K. Liu, Y. Zhu, P. Li, Q. Wang, B. Liu, S. Chen, H. Li, L. Zhu, H. Li, J. Fu, Y. Chen, E. Pensa, J. Hu, Y.-R. Lu, T.-S. Chan, E. Cortes, M. Liu, Angew. Chem. Int. Ed., 2022, 61, e202113664.
[23]	J. Wang, W. Fang, Y. Hu, Y. Zhang, J. Dang, Y. Wu, B. Chen, H. Zhao, Z. Li, Appl. Catal. B, 2021, 298, 120490.
[24]	D. Wang, Q. Li, C. Han, Z. Xing, X. Yang, Appl. Catal. B, 2019, 249, 91-97.
[25]	Y. Zhao, X. Zhang, Y. Gao, Z. Chen, Z. Li, T. Ma, Z. Wu, L. Wang, S. Feng, Small, 2022, 18, 2105168.
[26]	L. Gao, X. Wang, Z. Xie, W. Song, L. Wang, X. Wu, F. Qu, D. Chen, G. Shen, J. Mater. Chem. A, 2013, 1, 7167-7173.
[27]	G. Kresse, J Furthmüller. Phys. Rev. B, 1996, 54, 11169-11186.
[28]	J. P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett., 1996, 77, 3865-3868.
[29]	G. Kresse, D. Joubert, Phys. Rev. B, 1999, 59, 1758-1775.
[30]	P. E. Blöchl, Phys. Rev. B, 1994, 50, 17953-17979.
[31]	S. Grimme, J. Antony, S. Ehrlich, H. Krieg, J. Chem. Phys., 2010, 132, 154104
[32]	J. K. Nørskov, J. Rossmeisl, A. Logadottir, L. Lindqvist, J. R. Kitchin, T. Bligaard, H. Jonsson, J. Phys. Chem. B, 2004, 108, 17886-17892.
[33]	G. Henkelman, B. P. Uberuaga, H. Jonsson, J. Chem. Phys., 2000, 113, 9901-9904.
[34]	Y. Liu, L. Zhao, J. Su, M. Li, L. Guo, ACS Appl. Mater. Interfaces, 2015, 7, 3532-3538.
[35]	L. Peng, L. Su, X. Yu, R. Wang, X. Cui, H. Tian, S. Cao, B. Y. Xia, J. Shi, Appl. Catal. B, 2022, 308, 121229.
[36]	T. Xu, K. C. Adamsen, Z. Li, L. Lammich, J. V. Lauritsen, S. Wendt, J. Phys. Chem. C, 2022, 126, 2493-2502.
[37]	C. Guo, S. Yin, L. Huang, T. Sato, ACS Appl. Mater. Interfaces, 2011, 3, 2794-2799.
[38]	L. Yao, C. Zhang, N. Hu, L. Zhang, Z. Zhou, Y. Zhang, Electrochim. Acta, 2019, 295, 14-21.
[39]	M. Ronda-Leal, C. Espro, N. Lazaro, M. Selva, A. Perosa, S. M. Osman, A. Pineda, R. Luque, D. Rodriguez-Padron, Mater. Today Chem., 2022, 24, 100873.
[40]	J. J. Chen, N. Winograd, Surf. Sci., 1995, 326, 285-300.
[41]	W. Peng, M. Luo, X. Xu, K. Jiang, M. Peng, D. Chen, T.-S. Chan, Y. Tan, Adv. Energy Mater., 2020, 10, 2001364.
[42]	W. Huang, J. Kang, T. Chen, D. Pang, L. Wang, H. Wei, C. Yang, D. Zhang, L. Guo, Nano Res., 2022, 15, 4320-4326.
[43]	T. Kim, B. Song, A. J. G. Lunt, G. Cibin, A. J. Dent, L. Lu, A. M. Korsunsky, Chem. Mater., 2016, 28, 4191-4203.
[44]	Z. Kou, T. Wang, H. Wu, L. Zheng, S. Mu, Z. Pan, Z. Lyu, W. Zang, S. J. Pennycook, J. Wang, Small, 2019, 15, 1900248.
[45]	H. Yin, Z. Chen, Y. Peng, S. Xiong, Y. Li, H. Yamashita, J. Li, Angew. Chem. Int. Ed., 2022, 61, e202114242.
[46]	H. Wu, Q. Liu, L. Zhang, Y. Tang, G. Wang, G. Mao, ACS Appl. Energy Mater., 2021, 4, 12508-12514.
[47]	Y. Liu, N. Chen, W. Li, M. Sun, T. Wu, B. Huang, X. Yong, Q. Zhang, L. Gu, H. Song, R. Bauer, J. S. Tse, S.-Q. Zang, B. Yang, S. Lu, SmartMat, 2022, 3, 249-259.
[48]	Y. Ding, K.-W. Cao, J.-W. He, F.-M. Li, H. Huang, P. Chen, Y. Chen, Chin. J. Catal., 2022, 43, 1535-1543.
[49]	Q. He, D. Tian, H. Jiang, D. Cao, S. Wei, D. Liu, P. Song, Y. Lin, L. Song, Adv. Mater., 2020, 32, 1906972.
[50]	J. Qin, C. Xi, R. Zhang, T. Liu, P. Zou, D. Wu, Q. Guo, J. Mao, H. Xin, J. Yang, ACS Catal., 2021, 11, 4486-4497.
[51]	C.-F. Li, T.-Y. Shuai, L.-R. Zheng, H.-B. Tang, J.-W. Zhao, G.-R. Li, Chem. Eng. J., 2023, 451, 138618.
[52]	L. Xie, X. Ren, Q. Liu, G. Cui, R. Ge, A. M. Asiri, X. Sun, Q. Zhang, L. Chen, J. Mater. Chem. A, 2018, 6, 1967-1970.
[53]	C. Miao, Y. Zang, H. Wang, X. Zhuang, N. Han, Y. Yin, Y. Ma, M. Chen, Y. Dai, S. Yip, J. C. Ho, Z.-X. Yang, Adv. Mater. Interfaces, 2022, 9, 2200739.
[54]	Z. Wu, L. Liu, Z. Zhao, C. Yang, S. Mu, H. Zhou, X. Luo, T. Ma, S. Li, C. Zhao, Small, 2023, 19, 2204738.
[55]	W. Zhao, C. Luo, Y. Lin, G.-B. Wang, H. M. Chen, P. Kuang, J. Yu, ACS Catal., 2022, 12, 5540-5548.

钒掺杂钨青铜内通道氨配位的钌单原子用于高效析氢反应

Atomic Ru coordinated by channel ammonia in V-doped tungsten bronze for highly efficient hydrogen-evolution reaction

RichHTML

PDF

Supporting Information

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

图/表 4

参考文献

相关文章 15

编辑推荐

Metrics

[1]	王潇涵, 田汉, 余旭, 陈立松, 崔香枝, 施剑林. 非晶相电催化剂在电解水领域的研究进展[J]. 催化学报, 2023, 51(8): 5-48.
[2]	陈斌, 蒋亚飞, 肖海, 李隽. 石墨炔负载的双金属单团簇催化剂用于碱性析氢反应[J]. 催化学报, 2023, 50(7): 306-313.
[3]	詹麒尼, 帅婷玉, 徐慧民, 黄陈金, 张志杰, 李高仁. 单原子催化剂的合成及其在电化学能量转换中的应用[J]. 催化学报, 2023, 47(4): 32-66.
[4]	Sue-Faye Ng, 陈星竹, Joel Jie Foo, 熊墨, Wee-Jun Ong. 2D氮化碳: 通过调节非金属硼掺杂C₃N₅阐明宽酸性及碱性pH范围的光催化析氢的反应机理[J]. 催化学报, 2023, 47(4): 150-160.
[5]	李卓根, 张伟斌, 朱陆军, 高健智, 石先进, 黄宇, 刘鹏, 朱刚强. 通过实验和理论验证Pt⁰/SrTiO_3‒_δ复合催化剂双反应路径促进CO₂还原[J]. 催化学报, 2023, 46(3): 113-124.
[6]	刘玥, 章伟, 刘海超. 三氧化钨基催化剂在纤维素选择性转化合成二元醇反应中的活性相态[J]. 催化学报, 2023, 46(3): 56-63.
[7]	刘华, 康磊磊, 王华, 蒋齐可, 刘晓艳, 王爱琴. 硫酸化氧化锆负载的Ru单原子催化甲烷直接转化制甲醇[J]. 催化学报, 2023, 46(3): 64-71.
[8]	王妮, 张学鹏, 韩金秀, 雷海涛, 张清鑫, 张航, 张伟, 曹睿. 第二配位层磺酸根在电催化析氢反应中的作用[J]. 催化学报, 2023, 45(2): 88-94.
[9]	杨竣皓, 安露露, 王双, 张辰浩, 罗官宇, 陈应泉, 杨会颖, 王得丽. 层状双氢氧化物基电解水催化剂的缺陷工程调控策略[J]. 催化学报, 2023, 55(12): 116-136.
[10]	苏慧, 姜静, 宋少佳, 安博涵, 李宁, 高旸钦, 戈磊. 过渡金属硫化物相关电催化剂的设计与应用研究[J]. 催化学报, 2023, 44(1): 7-49.
[11]	白雪, 管景奇. 过渡金属碳氮化物在电催化领域的应用: 改性和杂化[J]. 催化学报, 2022, 43(8): 2057-2090.
[12]	黄楚强, 周建清, 段丁槊, 周前程, 汪杰明, 彭博文, 余罗, 余颖. 异质原子在碱性电解水催化剂中的作用——反应机理[J]. 催化学报, 2022, 43(8): 2091-2110.
[13]	李鹏, 赵国强, 程宁燕, 夏力学, 李晓宁, 陈亚平, 劳梦梦, 程振祥, 赵焱, 徐迅, 姜银珠, 潘洪革, 窦士学, 孙文平. 过渡金属单原子功能化碳载体促进碱性氢电催化反应动力学[J]. 催化学报, 2022, 43(5): 1351-1359.
[14]	鲁利梅, 张以河, 陈振胜, 冯峰, 滕凯旋, 张舒婷, 庄佳琳, 安琪. 界面N-C负载三元Zn-Co-Ni合金纳米材料对电催化水分解的协同增强效应[J]. 催化学报, 2022, 43(5): 1316-1323.
[15]	王兰, 公宁, 周洲, 张启成, 彭文朝, 李阳, 张凤宝, 范晓彬. MOF衍生的分层多孔三维N-CoP_x/Ni₂P大电流密度下加速析氢[J]. 催化学报, 2022, 43(4): 1176-1183.